ElectrochemicalImpedanceSpectroscopy

Category:OSWd30d9de0b9bf4919a0220394df9c3672
ElectrochemicalImpedanceSpectroscopy [OSWd30d9de0b9bf4919a0220394df9c3672]
ID OSWd30d9de0b9bf4919a0220394df9c3672
UUID d30d9de0-b9bf-4919-a022-0394df9c3672
Label ElectrochemicalImpedanceSpectroscopy
Machine compatible name ElectrochemicalImpedanceSpectroscopy
Statements (outgoing)
Statements (incoming)

Description

Electrochemical measurement method of the complex impedance of an electrochemical system as a function of the frequency of a small amplitude (normally 5 to 10 mV) sinusoidal voltage perturbation superimposed on a fixed value of applied potential or on the open circuit potential.

Item
Type(s)/Category(s) EmmoTerm
Term
EmmoTerm
Comment
  • Impedimetric sensors are based on measurement of a concentration-dependent parameter taken from analysis of the respective electrochemical impedance spectra, or from the impedance magnitudes at a chosen fixed frequency. [en]
  • The sinusoidal current response lags behind the sinusoidal voltage perturbation by a phase angle φ. Resistances (e.g. to charge transfer) give a response in phase with the voltage perturbation; capacitances (e.g. double layer) give a response 90° out of phase; combinations of resistances and capacitances give phase angles between 0 and 90°. Plots of the out of phase vs. the in phase component of the impedance for all the frequencies tested are called complex plane (or Nyquist) plots. Plots of the phase angle and the magnitude of the impedance vs. the logarithm of perturbation frequency are called Bode diagrams. Complex plane plots are the more commonly used for electrochemical sensors. [en]
Superclass
  • Impedimetry
  • Alternative label
  • EIS [en]
  • URIhttp://emmo.info/electrochemistry#electrochemistry_d30d9de0_b9bf_4919_a022_0394df9c3672
    jsondata
    uuid"d30d9de0-b9bf-4919-a022-0394df9c3672"
    name"ElectrochemicalImpedanceSpectroscopy"
    label
    text"ElectrochemicalImpedanceSpectroscopy"
    lang"en"
    description
    text"Electrochemical measurement method of the complex impedance of an electrochemical system as a function of the frequency of a small amplitude (normally 5 to 10 mV) sinusoidal voltage perturbation superimposed on a fixed value of applied potential or on the open circuit potential."
    lang"en"
    type
    "Category:OSW57beed5e1294434ba77bb6516e461456"
    uri"http://emmo.info/electrochemistry#electrochemistry_d30d9de0_b9bf_4919_a022_0394df9c3672"
    altLabel
    text"EIS"
    lang"en"
    comment
    text"Impedimetric sensors are based on measurement of a concentration-dependent parameter taken from analysis of the respective electrochemical impedance spectra, or from the impedance magnitudes at a chosen fixed frequency."
    lang"en"
    text"The sinusoidal current response lags behind the sinusoidal voltage perturbation by a phase angle φ. Resistances (e.g. to charge transfer) give a response in phase with the voltage perturbation; capacitances (e.g. double layer) give a response 90° out of phase; combinations of resistances and capacitances give phase angles between 0 and 90°. Plots of the out of phase vs. the in phase component of the impedance for all the frequencies tested are called complex plane (or Nyquist) plots. Plots of the phase angle and the magnitude of the impedance vs. the logarithm of perturbation frequency are called Bode diagrams. Complex plane plots are the more commonly used for electrochemical sensors."
    lang"en"
    subClassOf
    "http://emmo.info/electrochemistry#electrochemistry_07ad0aff_ab59_442d_9c0a_7f8c5cba8982"

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